While talking to Princess Twilight Sparkle, a Royal Guard refers to Princess Celestia as 'Sunbutt'. He is quick to explain how he came to learn of the nickname, and suggests that Twilight should talk to Princess Luna.
So she does, whereupon she finds that Luna is all too happy to share a story with her...
Everypony thinks that Celestia is called 'Sunbutt' because of her cutie mark. Only Luna knows the real story, though, and now she's going to share it with Twilight.
(Sequel to 'The Origin Of Sunbutt'.) Now it's Celestia's turn to share a story with Princess Twilight...